Изоморфизм уравнений диссипативных свойств растворов электролитов
Таблица 8
Результаты оценок коэффициента диффузии раствора NaCl
C mol/l |
Dтеор (30) |
Dтеор (35) |
Dтеор (38) |
Dтеор (40) |
Dлит [10] |
Dлит [11] |
0,0000 |
1,4539 |
1,3912 |
1,3912 |
1,4539 |
1,3910 | |
0,0010 |
1,4227 |
1,3690 |
1,3535 |
1,4103 |
1,3694 |
1,3738 |
0,0030 |
1,4019 |
1,3546 |
1,3300 |
1,3830 |
1,3565 |
1,3565 |
0,0050 |
1,3871 |
1,3455 |
1,3144 |
1,3649 |
1,3478 |
1,3478 |
0,0100 |
1,3628 |
1,3307 |
1,2904 |
1,3367 |
1,3349 |
1,3392 |
0,0500 |
1,2769 |
1,2895 |
1,2242 |
1,2559 |
1,3020 |
1,3046 |
0,0700 |
1,2604 |
1,2821 |
1,2181 |
1,2460 |
1,3046 |
1,3046 |
0,1000 |
1,2273 |
1,2764 |
1,2017 |
1,2250 |
1,2813 | |
0,2000 |
1,1694 |
1,2760 |
1,1920 |
1,2057 | ||
0,2200 |
1,2775 |
1,2787 | ||||
0,5000 |
1,0764 |
1,3146 |
1,2086 |
1,2085 | ||
0,5700 |
1,3259 |
1,2701 |
1,2701 | |||
1,0000 |
0,9861 |
1,4040 |
1,2493 |
1,2395 |
1,2822 |
1,2787 |
1,5000 |
0,9182 |
1,5157 |
1,2874 |
1,2741 | ||
2,0000 |
0,8590 |
1,6536 |
1,3216 |
1,3078 |
1,3098 | |
3,0000 |
0,7539 |
2,0075 |
1,3724 |
1,3631 |
1,3522 | |
4,0000 |
0,6580 |
2,4422 |
1,3787 |
1,3781 |
1,3772 | |
5,0000 |
0,5687 |
2,9138 |
1,3259 |
1,3358 |
1,3738 | |
5,5203 |
3,1569 |
Таблица 9
Результаты оценок вязкости раствора NaCl
C mol/l |
теор (29) |
теор (41) |
теор (41а) |
теор (42) |
лит [10] |
лит [12] |
эксп |
0,0000 |
0,9507 |
0,9985 |
0,9555 |
1,0320 |
0,8937 |
0,9545 | |
0,0010 |
0,9715 |
1,0264 |
0,9850 |
1,0307 |
0,9544 |
0,882 | |
0,0030 |
0,9859 |
1,0445 |
1,0045 |
1,0299 | |||
0,0050 |
0,9965 |
1,0569 |
1,0178 |
1,0293 | |||
0,0100 |
1,0142 |
1,0766 |
1,0393 |
1,0284 |
0,896 | ||
0,0500 |
1,0824 |
1,1348 |
1,1062 |
1,0254 | |||
0,0700 |
1,0966 |
1,1405 |
1,1149 |
1,0248 | |||
0,1000 |
1,1262 |
1,1561 |
1,1340 |
1,0242 |
0,9020 |
0,9583 |
0,9467 |
0,1250 |
1,0239 |
0,9053 |
0,9598 | ||||
0,2000 |
1,1819 |
1,1655 |
1,1522 |
1,0237 |
0,9653 | ||
0,2200 |
1,0238 | ||||||
0,2500 |
1,0240 |
0,9154 |
0,9636 | ||||
0,5000 |
1,2841 |
1,1494 |
1,1496 |
1,0271 |
0,9361 |
0,9717 |
1,0031 |
0,8860 |
1,0345 |
0,9815 |
0,9831 | ||||
1,0000 |
1,4018 |
1,1120 |
1,1208 |
1,0370 |
1,063 | ||
1,5000 |
1,5053 |
1,0791 |
1,0904 |
1,0486 |
1,0276 |
0,9984 | |
1,8300 |
1,0568 |
1,0760 |
1,0051 | ||||
2,0000 |
1,6091 |
1,0512 |
1,0622 |
1,0610 |
1,0773 |
1,0091 |
1,12 |
3,0000 |
1,8334 |
1,0122 |
1,0191 |
1,0870 | |||
4,0000 |
2,1006 |
1,0077 |
1,0081 |
1,1138 | |||
5,0000 |
2,4306 |
1,0477 |
1,0400 |
1,1411 | |||
5,5203 |
1,1555 |