Расчеты и прогнозирование свойств 2-Метил-3,3-диэтилпентана, Циклобутана, о-Ксилол, 1,2-диметилбензола, 4-Метилпиридина
Корреляция Риделя
где 
приведенная температура кипения.
|
А |
В |
С |
D |
θ |
αc |
ψ |
|
10,0617 |
10,3492 |
-4,8855 |
0,2875 |
-0,2875 |
7,1885 |
2,2628 |
|
Т |
Тr |
Pvp,r |
Pvp, bar |
|
298 |
0.46 |
0.0002 |
0.0079 |
|
323 |
0.50 |
0.0007 |
0.0305 |
|
348 |
0.54 |
0.0021 |
0.0945 |
|
373 |
0.58 |
0.0056 |
0.2458 |
|
398 |
0.62 |
0.0127 |
0.5568 |
|
423 |
0.65 |
0.0256 |
1.1268 |
|
448 |
0.69 |
0.0473 |
2.0805 |
|
473 |
0.73 |
0.0810 |
3.5624 |
|
498 |
0.77 |
0.1303 |
5.7323 |
|
523 |
0.81 |
0.1992 |
8.7638 |
|
548 |
0.85 |
0.2920 |
12.8470 |
|
573 |
0.89 |
0.4136 |
18.2002 |
|
598 |
0.93 |
0.5702 |
25.0894 |
|
623 |
0.96 |
0.7696 |
33.8611 |
Корреляция Амброуза-Уолтона.
где 
|
Т |
Тr |
τ |
f(0) |
f(1) |
f(2) |
Pvp,r |
Pvp, bar |
|
298 |
0.46 |
0.54 |
-6.2496 |
-8.1557 |
-0.3377 |
0.0002 |
0.0092 |
|
323 |
0.50 |
0.50 |
-5.3381 |
-6.6253 |
-0.2461 |
0.0008 |
0.0347 |
|
348 |
0.54 |
0.46 |
-4.5656 |
-5.4035 |
-0.1693 |
0.0024 |
0.1051 |
|
373 |
0.58 |
0.42 |
-3.9024 |
-4.4161 |
-0.1074 |
0.0061 |
0.2676 |
|
398 |
0.62 |
0.38 |
-3.3264 |
-3.6093 |
-0.0599 |
0.0135 |
0.5939 |
|
423 |
0.65 |
0.35 |
-2.8209 |
-2.9429 |
-0.0255 |
0.0269 |
1.1816 |
|
448 |
0.69 |
0.31 |
-2.3729 |
-2.3869 |
-0.0028 |
0.0489 |
2.1524 |
|
473 |
0.73 |
0.27 |
-1.9726 |
-1.9184 |
0.0100 |
0.0829 |
3.6487 |
|
498 |
0.77 |
0.23 |
-1.6119 |
-1.5198 |
0.0146 |
0.1325 |
5.8301 |
|
523 |
0.81 |
0.19 |
-1.2843 |
-1.1775 |
0.0131 |
0.2016 |
8.8720 |
|
548 |
0.85 |
0.15 |
-0.9848 |
-0.8804 |
0.0076 |
0.2947 |
12.9654 |
|
573 |
0.89 |
0.11 |
-0.7087 |
-0.6199 |
0.0003 |
0.4164 |
18.3231 |
|
598 |
0.93 |
0.07 |
-0.4523 |
-0.3885 |
-0.0061 |
0.5726 |
25.1939 |
|
623 |
0.96 |
0.04 |
-0.2117 |
-0.1794 |
-0.0081 |
0.7705 |
33.9003 |
